Description
Catalogue Number	106009
Synonyms	MeOH, Hydroxymethane, Methyl alcohol, Carbinol
Overview	EMSURE® grade solvents are suitable for a broad spectrum of classical lab applications, and are frequently used in regulated and highly demanding lab applications. EMSURE®provides worldwide best and most extensive product specifications. We declare our EMSURE® range to be in compliance with the ACS, with the reagent part of the European Pharmacopoeia (Reag. Ph Eur) and also with the ISO standards.

Product Information
CAS number	67-56-1
EC index number	603-001-00-X
EC number	200-659-6
Grade	ACS,ISO,Reag. Ph Eur
Hill Formula	CH₄O
Chemical formula	CH₃OH
Molar Mass	32.04 g/mol
HS Code	2905 11 00
Structure formula Image

Applications
Application	Methanol for analysis EMSURE® ACS,ISO,Reag. Ph Eur. CAS 67-56-1, chemical formula CH₃OH, molar mass 32.04 g/mol.

Physicochemical Information
Boiling point	64.5 °C (1013 hPa)
Density	0.792 g/cm3 (20 °C)
Evaporation number	1.9
Explosion limit	5.5 - 44 %(V)
Flash point	9.7 °C
Ignition temperature	420 °C DIN 51794
Melting Point	-98 °C
Vapor pressure	128 hPa (20 °C)

Toxicological Information
LD 50 oral	LD50 Rat 5628 mg/kg
LD 50 dermal	LD50 Rabbit 17100 mg/kg

Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H225: Highly flammable liquid and vapour. H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled. H370: Causes damage to organs.
Precautionary Statement(s)	P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240: Ground/bond container and receiving equipment. P280: Wear protective gloves/ protective clothing. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician. P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Signal Word	Danger
RTECS	PC1400000
Storage class	3 Flammable liquids
WGK	WGK 2 water endangering
Disposal	1 Strongly contaminated halogen-free organic solvents: container A.

Safety Information
Hazard Symbols	Toxic Flammable
Categories of danger	highly flammable, toxic
R Phrase	R 11-23/24/25-39/23/24/25 Highly flammable.Toxic by inhalation, in contact with skin and if swallowed.Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
S Phrase	S 7-16-36/37-45 Keep container tightly closed.Keep away from sources of ignition - No smoking.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Storage and Shipping Information
Storage	Store at +5°C to +30°C.

Transport Information
Declaration (railroad and road) ADR, RID	UN 1230 , 3 (6.1), II
Declaration (transport by air) IATA-DGR	UN 1230 , 3 (6.1), II
Declaration (transport by sea) IMDG-Code	UN 1230 , 3 (6.1), II

Specifications
Purity (GC)	≥ 99.9 %
Identity (IR)	conforms
Appearance	clear
Colour	≤ 10 Hazen
Solubility in water	conforms
Acidity	≤ 0.0002 meq/g
Alkalinity	≤ 0.0002 meq/g
Density (d 20 °C/20 °C)	0.791 - 0.793
Boiling point	64 - 65 °C
Benzene (impurity A) (GC)	≤ 2 ppm
Ethanol (GC)	≤ 0.05 %
Acetone	≤ 0.001 %
Acetaldehyde	≤ 0.001 %
Formaldehyde	≤ 0.001 %
Readily carbonizable substances	conforms
Carbonyl compounds (as CO)	≤ 0.001 %
Chloride (Cl)	≤ 0.5 ppm
Sulphate (SO₄)	≤ 1 ppm
Substances reducing potassium permanganate (as O)	≤ 0.00025 %
Ag (Silver)	≤ 0.000002 %
Al (Aluminium)	≤ 0.00005 %
As (Arsenic)	≤ 0.000002 %
Au (Gold)	≤ 0.000002 %
Ba (Barium)	≤ 0.00001 %
Be (Beryllium)	≤ 0.000002 %
Bi (Bismuth)	≤ 0.000002 %
Ca (Calcium)	≤ 0.00005 %
Cd (Cadmium)	≤ 0.000005 %
Co (Cobalt)	≤ 0.000002 %
Cr (Chromium)	≤ 0.000002 %
Cu (Copper)	≤ 0.000002 %
Fe (Iron)	≤ 0.00001 %
Ga (Gallium)	≤ 0.000002 %
In (Indium)	≤ 0.000002 %
Li (Lithium)	≤ 0.000002 %
Mg (Magnesium)	≤ 0.00001 %
Mn (Manganese)	≤ 0.000002 %
Mo (Molybdenum)	≤ 0.000002 %
Ni (Nickel)	≤ 0.000002 %
Pb (Lead)	≤ 0.00001 %
Pt (Platinum)	≤ 0.000005 %
Sn (Tin)	≤ 0.00001 %
Ti (Titanium)	≤ 0.000002 %
Tl (Thallium)	≤ 0.000002 %
V (Vanadium)	≤ 0.000002 %
Zn (Zinc)	≤ 0.00001 %
Zr (Zirconium)	≤ 0.000002 %
Evaporation residue	≤ 0.0005 %
Water	≤ 0.05 %
ACS, ISO, Reag Ph Eur

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MERCK 106009 Methanol for analysis EMSURE® ACS,ISO,Reag. Ph Eur. CAS 67-56-1 2,5 Litre Cam Şişe

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