Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H290: May be corrosive to metals. H314: Causes severe skin burns and eye damage. H335: May cause respiratory irritation.
Precautionary Statement(s)	P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Storage class	8B Non-combustible, corrosive hazardous materials
WGK	WGK 1 slightly water endangering
Disposal	12 Inorganic acids and anhydrides thereof should first be diluted or hydrolyzed by stirring carefully into ice water and then neutralized (protective gloves, fume cupboard!) with sodium hydroxide solution (Cat. No. 105587). Before filling into container D, check the pH with pH universal indicator strips (Cat. No. 109535). Fuming sulfuric acid should be carefully stirred dropwise into 40 % sulfuric acid (Cat. No. 109286). Ensure that plenty of ice is available for cooling! When sufficiently cool, treat the highly concentrated sulfuric acid as described above. Analogous to this procedure, other anhydrides can be converted into their corresponding acids. Acid gases (e.g. hydrogen halide, chlorine, phosgene, sulfur dioxide) can be introduced into dilute sodium hydroxide solution and after neutralization disposed of in container D.

Safety Information
Hazard Symbols	Corrosive
Categories of danger	corrosive
R Phrase	R 34-37 Causes burns.Irritating to respiratory system.
S Phrase	S 26-36/37/39-45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Storage and Shipping Information
Storage	Store at +2°C to +25°C.

Transport Information
Declaration (railroad and road) ADR, RID	UN 1789 , 8, II
Declaration (transport by air) IATA-DGR	UN 1789 , 8, II
Declaration (transport by sea) IMDG-Code	UN 1789 , 8, II, Segregation Group: 1 (Acids)

Specifications
Assay (alkalimetric)	36.5 - 38.0 %
Identity	passes test
Appearance	passes test
Colour	≤ 10 Hazen
Bromide (Br)	≤ 50 ppm
Free chlorine (Cl)	≤ 1 ppm
Heavy metals (as Pb)	≤ 1 ppm
Sulphate (SO₄)	≤ 1 ppm
Sulfite (SO₃)	≤ 1 ppm
As (Arsenic)	≤ 0.01 ppm
Fe (Iron)	≤ 0.2 ppm
NH₄ (Ammonium)	≤ 3 ppm
Residue on ignition (as SO₄)	≤ 5 ppm
Expiry date: see product label

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MERCK 101834 Hydrochloric acid fuming 37% for analysis EMPARTA ACS

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